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GC/MS analysis for HAAs was carried out by selected ion monitoring using a Finnigan MAT 90 GC/MS fitted with a DB-1701 30m × 0.32 mmid (0.25 µ film) column by injection of 3 µL aliquots (Varian SPI injector). The GC operating parameters were: injector - 100°C increased to 240°C at 100°/min, hold 24 min; oven - 40°C held for 3 min, increased to 140°C at 3.3°/min, then to 180°C at 23°/min. The ions monitored (mass resolution 1000) for each target HAA were: monochloroacetic acid - 49,77,79; dichloroacetic acid - 83,85; trichloroacetic acid - 117,119,121; monobromoacetic acid - 93,95; dibro-moacetic acid - 171,173,175; tribromoacetic acid - 251,253; bromochloroacetic acid - 127,129; bromodichloroacetic acid - 141,161,163; chlorodibromoacetic acid - 207,209. DBP quantification was carried out by using rela ti ve response factors derived from the analysis of fortified water samples.
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